So with that said, let's go back to the question of how do we know if one of these guys are going to decay in some way. That, you know, maybe this guy will decay this second. Remember, isotopes, if there's carbon, can come in 12, with an atomic mass number of 12, or with 14, or I mean, there's different isotopes of different elements. So the carbon-14 version, or this isotope of carbon, let's say we start with 10 grams. Well we said that during a half-life, 5,740 years in the case of carbon-14-- all different elements have a different half-life, if they're radioactive-- over 5,740 years there's a 50%-- and if I just look at any one atom-- there's a 50% chance it'll decay. Now after another half-life-- you can ignore all my little, actually let me erase some of this up here. So we'll have even more conversion into nitrogen-14. So now we're only left with 2.5 grams of c-14. Well we have another two and a half went to nitrogen. So after one half-life, if you're just looking at one atom after 5,740 years, you don't know whether this turned into a nitrogen or not. Scientists look at half-life decay rates of radioactive isotopes to estimate when a particular atom might decay. And so, like everything in chemistry, and a lot of what we're starting to deal with in physics and quantum mechanics, everything is probabilistic. So one of the neutrons must have turned into a proton and that is what happened. And you might say, oh OK, so maybe-- let's see, let me make nitrogen magenta, right there-- so you might say, OK, maybe that half turns into nitrogen. And over 5,740 years, you determine that there's a 50% chance that any one of these carbon atoms will turn into a nitrogen atom. And we could keep going further into the future, and after every half-life, 5,740 years, we will have half of the carbon that we started. Now, if you look at it over a huge number of atoms. But after two more years, how many are we going to have? So this is t equals 3 I'm sorry, this is t equals 4 years. And maybe not carbon-12, maybe we're talking about carbon-14 or something. And then nothing happens for a long time, a long time, and all of a sudden two more guys decay. And the atomic number defines the carbon, because it has six protons. If they say that it's half-life is 5,740 years, that means that if on day one we start off with 10 grams of pure carbon-14, after 5,740 years, half of this will have turned into nitrogen-14, by beta decay. What happens over that 5,740 years is that, probabilistically, some of these guys just start turning into nitrogen randomly, at random points. So if we go to another half-life, if we go another half-life from there, I had five grams of carbon-14. So now we have seven and a half grams of nitrogen-14. This exact atom, you just know that it had a 50% chance of turning into a nitrogen. Now you could say, OK, what's the probability of any given molecule reacting in one second? But we're used to dealing with things on the macro level, on dealing with, you know, huge amounts of atoms. So I have a description, and we're going to hopefully get an intuition of what half-life means. And how does this half know that it must stay as carbon? So if you go back after a half-life, half of the atoms will now be nitrogen. Then all of a sudden you can use the law of large numbers and say, OK, on average, if each of those atoms must have had a 50% chance, and if I have gazillions of them, half of them will have turned into nitrogen. How much time, you know, x is decaying the whole time, how much time has passed? I mean, maybe if we really got in detail on the configurations of the nucleus, maybe we could get a little bit better in terms of our probabilities, but we don't know what's going on inside of the nucleus, so all we can do is ascribe some probabilities to something reacting. And it does that by releasing an electron, which is also call a beta particle. And I've actually seen this drawn this way in some chemistry classes or physics classes, and my immediate question is how does this half know that it must turn into nitrogen? So that after 5,740 years, the half-life of carbon, a 50% chance that any of the guys that are carbon will turn to nitrogen. But we'll always have an infinitesimal amount of carbon. Let's say I'm just staring at one carbon atom. You know, I've got its nucleus, with its c-14. I mean, if you start approaching, you know, Avogadro's number or anything larger-- I erased that. After two years, how much are we going to have left? And then after two more years, I'll only have half of that left again.
Date Created: 05/09/16 Weekly Assignment 14 (included in Final Exam) Weekly Assignment 14 (included in Final Exam) Due: pm on Friday, May 13, 2016 To understand how points are awarded, read theing Policy for this assignment. Electron shells The terminology for electron shells is based exclusively on the principal quantum number, \texttip.
A useful application of half-lives is radioactive dating.
This has to do with figuring out the age of ancient things.
About one carbon atom in a trillion (10) contains a radioactive nucleus with 6 protons and 8 neutrons — carbon 14.
This rare, unstable isotope is produced from ordinary nitrogen 14.
Carbon-14 dating can be used on objects ranging from a few hundred years old to 50,000 years old.